AssayIndex
Cross-section

SLU-PP-332 impurity profile

Every named species the index has reported alongside SLU-PP-332, how often, at what level, and what its presence implies about the synthesis or the handling. Reporting threshold is 0.05 % area; anything below it is invisible to this page and is silently added to the main peak.

22 recordsmedian 98.88 %spec 98.0 %
Median total impurities 1.13% n=22
Median largest single 0.60% n=22
Worst single observed 0.91% n=22
Named species observed 4 / 4 n=4
Named speciesΔRT (min)Δ mass (Da)Seen inMedian % areaMax % area
hydrolysed ester (+18 Da)-1.24+18.011100%0.200.91
sulfoxide (+16 Da)-0.72+15.995100%0.180.59
des-methyl analogue (−14 Da)-0.36-14.016100%0.150.85
residual DMSO (process solvent)-10.10mass-identical100%0.390.84

hydrolysed ester (+18 Da)

Retention offset from the main peak
-1.24 min on RG-2
Mass difference
+18.011 Da
Reported in
22 of 22 records (100 %)
Level when reported
median 0.20 %, max 0.91 %
How it separates
Baseline-resolved on the reference method.

sulfoxide (+16 Da)

Retention offset from the main peak
-0.72 min on RG-2
Mass difference
+15.995 Da
Reported in
22 of 22 records (100 %)
Level when reported
median 0.18 %, max 0.59 %
How it separates
Baseline-resolved on the reference method.

des-methyl analogue (−14 Da)

Retention offset from the main peak
-0.36 min on RG-2
Mass difference
-14.016 Da
Reported in
22 of 22 records (100 %)
Level when reported
median 0.15 %, max 0.85 %
How it separates
Baseline-resolved on the reference method.

residual DMSO (process solvent)

Retention offset from the main peak
-10.10 min on RG-2
Mass difference
mass-identical — chromatography only
Reported in
22 of 22 records (100 %)
Level when reported
median 0.39 %, max 0.84 %
How it separates
Chromatography only. A gradient long enough to separate it; no mass spectrometer of any resolution will.

Degradation pathways

Degradants are a handling finding rather than a synthesis finding. A lot that shipped clean and arrived oxidised tells you about the courier, not the chemist.

  • ester hydrolysis in aqueous suspension
  • thioether oxidation