AssayIndex
Cross-section

CJC-1295 (no DAC) impurity profile

Every named species the index has reported alongside CJC-1295 (no DAC), how often, at what level, and what its presence implies about the synthesis or the handling. Reporting threshold is 0.05 % area; anything below it is invisible to this page and is silently added to the main peak.

220 recordsmedian 99.09 %spec 98.0 %
Median total impurities 0.91% n=220
Median largest single 0.46% n=220
Worst single observed 1.75% n=220
Named species observed 5 / 5 n=5
Named speciesΔRT (min)Δ mass (Da)Seen inMedian % areaMax % area
native GRF (1-29) (−59 Da)-0.34-58.99598%0.121.75
deamidated (+1 Da)-0.24+0.98496%0.111.14
des-Tyr1 (−163 Da)-0.54-163.06394%0.161.34
truncated (1-24)-1.16-570.29187%0.111.46
acetyl adduct (+42 Da)+0.44+42.01178%0.070.70

native GRF (1-29) (−59 Da)

Retention offset from the main peak
-0.34 min on RG-2
Mass difference
-58.995 Da
Reported in
215 of 220 records (98 %)
Level when reported
median 0.12 %, max 1.75 %
How it separates
Baseline-resolved on the reference method.

deamidated (+1 Da)

Retention offset from the main peak
-0.24 min on RG-2
Mass difference
+0.984 Da
Reported in
211 of 220 records (96 %)
Level when reported
median 0.11 %, max 1.14 %
How it separates
Close-eluting on the reference method, and merged with the main peak on a short gradient. The index prints the resolution figure for such a pair and applies no criterion to it — where the two are not separated, what matters is that the integration convention is stated.

des-Tyr1 (−163 Da)

Retention offset from the main peak
-0.54 min on RG-2
Mass difference
-163.063 Da
Reported in
207 of 220 records (94 %)
Level when reported
median 0.16 %, max 1.34 %
How it separates
Baseline-resolved on the reference method.

truncated (1-24)

Retention offset from the main peak
-1.16 min on RG-2
Mass difference
-570.291 Da
Reported in
192 of 220 records (87 %)
Level when reported
median 0.11 %, max 1.46 %
How it separates
Baseline-resolved on the reference method.

acetyl adduct (+42 Da)

Retention offset from the main peak
+0.44 min on RG-2
Mass difference
+42.011 Da
Reported in
171 of 220 records (78 %)
Level when reported
median 0.07 %, max 0.70 %
How it separates
Baseline-resolved on the reference method.

Degradation pathways

Degradants are a handling finding rather than a synthesis finding. A lot that shipped clean and arrived oxidised tells you about the courier, not the chemist.

  • Asn8 deamidation — the reason the D-Ala/Gln/Ala/Leu substitutions exist
  • Asp-Gly aspartimide during synthesis